Allı, AbdulkadirArı, YurdagülGökçen, Muharrem2020-04-302020-04-3020160003-021X1558-9331https://doi.org/10.1007/s11746-016-2834-5https://hdl.handle.net/20.500.12684/3838Gokcen, Muharrem/0000-0001-9063-3028WOS: 000378904400003A poly(linolenic acid)-g-poly(tert-butyl acrylate) graft copolymer was synthesized from polymeric linolenic acid peroxide possessing peroxide groups in the main chain by free radical polymerization of tert-butyl acrylate. Graft copolymers having structures of poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate) were synthesized from polymeric linolenic acid, possessing peroxide groups on the main chain by the combination of free radical polymerization of tert-butyl acrylate and ring-opening polymerization of epsilon-caprolactone in one-pot. The obtained graft copolymers were characterized by proton nuclear magnetic resonance, gel permeation chromatography, thermal gravimetric analysis, differential scanning calorimetry, and scanning electron microscopy techniques. Furthermore, Au/n-Si diodes were fabricated with and without poly(linolenic acid)-g-poly(caprolactone)-g-poly(tert-butyl acrylate)-4 to form a new interfacial polymeric layer for the purpose of investigating this polymer's conformity in electronic applications. Some main electrical characteristics of these diodes were investigated using experimental current-voltage measurements in the dark and at room temperature.en10.1007/s11746-016-2834-5info:eu-repo/semantics/closedAccessAutoxidationOne-pot polymerizationLinolenic acidtert-Butyl acrylateepsilon-CaprolactoneElectrical propertiesArticle937895904WOS:000378904400003Q2Q2